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1 About the Author |
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1.1 Research on Organoborane Chemistry |
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1.2 Sketch of Professor Akira Suzuki's Life |
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1.3 Awards |
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1.4 List of Publications(1967-2003) |
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2 Organoboranes as Sources of Organic Radicals |
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2.1 Introduction |
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2.2 Reactions with α,β-Unsaturated Carbonyl Compounds |
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2.3 Oxygen‐Induced Reaction of Trialkylboranes with Alkyl Halides.A Facile Coupling of Allylic and Benzylic Halides via Triethylborane |
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2.4 A New Four‐Carbon‐Atom Homologation Involving the Free‐Radical Chain Reaction of 1,3-Butadiene Monoxide with Organoboranes |
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2.5 Two Novel Reactions of Monomeric Formaldehyde with Trialkylboranes.A Remarkable Rapid Elimination Diverted by Oxygen to a Free‐Radical Chain Addition |
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2.6 A Convenient Synthesis of α-Bromoketones from Vinyloxyboranes Obtained by the Reaction of Organoboranes with α,β-Unsaturated Ketones in the Presence of a Catalytic Amount of Oxygen |
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2.7 Oxygen‐Induced 1,4-Addition Reaction of Organoboranes to Crotonaldimine |
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2.8 Reaction of Organoboranes with 1-Acyl-2-vinylcyclopropanes in the Presence of Oxygen |
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2.9 Reaction of Organoboranes with d‐Carvone and l‐Perilialdehyde in the Presence of Oxygen.Evidence for Coordination between Organoboranes and α,β-Unsaturated Carbonyl Oxygen in their Oxygen‐Induced Free‐Radical Reaction Process |
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2.10 Reaction of Organoboranes with Iron(Ⅲ)Azide in the Presence of Hydrogen Peroxide.A Novel Synthesis of Azidoalkanes |
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3 Organic Syntheses Using Organoborates |
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3.1 Introduction |
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3.2 Preparation of Tetracoordinate Organoborates |
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3.3 Synthesis via Organoborates(R3B-X-Y)with Latent Leaving Groups(Y)in the α-Position |
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3.4 Synthesis via Alkynylborates and Alkenylborates |
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3.5 Synthesis via Copper(Ⅰ)Tetraorganoborates and Related Compounds |
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3.6 Miscellaneous Reactions |
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3.7 Summary |
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4 Haloboration of 1-Alkynes and Its Synthetic Application |
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4.1 Introduction |
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4.2 Organic Synthesis via Haloboration Adducts Prepared from B-Halo-9-BBN |
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4.3 Organic Synthesis via Haloboration Adducts Prepared from Tribromoborane |
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4.4 Conclusion |
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5 Palladium‐Catalyzed Cross‐Coupling Reactions of Organoboron Compounds with Organic Electrophiles |
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5.1 Introduction |
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5.2 Synthesis of Organoboron Reagents |
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5.3 Palladium‐Catalyzed Reactions of Organoboron Compounds Their Mechanism |
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5.4 Cross‐Coupling Reaction |
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5.5 Head‐to‐Tail Coupling |
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5.6 Carbonylative Coupling |
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5.7 Alkoxycarbonylation and Dimerization |
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5.8 Conclusion |
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